1 00:01:00,89 --> 00:01:05,92 The modern motion picture brings you. Education. Entertainment. 2 00:01:07,41 --> 00:01:11,74 That brings the world to the smallest town the poorest. 3 00:01:15,43 --> 00:01:19,00 In the street. Which bring these marvels to you. 4 00:01:22,82 --> 00:01:23,95 Artists and technicians. 5 00:01:24,41 --> 00:01:28,70 Put together the mixture of science which makes actors 6 00:01:28,70 --> 00:01:33,47 and sets and lights camera 7 00:01:33,48 --> 00:01:39,97 and cameras there is a roll of Motion Picture negatives. 8 00:01:40,50 --> 00:01:42,18 In this camera. 9 00:01:42,20 --> 00:01:49,01 The finished picture will be on another roll known as positive film. 10 00:01:49,03 --> 00:01:54,50 These delicate strips of with their light sensitive coating on the materials which 11 00:01:54,50 --> 00:01:58,42 records and transmit the creations of Hollywood to the world. 12 00:02:00,00 --> 00:02:02,16 This picture is the story of these films 13 00:02:03,20 --> 00:02:09,75 and of how the alchemy in Hollywood makes entertainment out of solar these 14 00:02:09,75 --> 00:02:14,64 buildings are some of the movie photo finishers of Motion Picture laboratories in 15 00:02:14,64 --> 00:02:20,23 Hollywood where you have taken a snapshot of Junior with your own camera you take 16 00:02:20,23 --> 00:02:24,33 your roll of film to the photo finish your next day. So you're finished pictures. 17 00:02:25,26 --> 00:02:30,36 This is just what happens to movie film from a studio camera the photographic 18 00:02:30,36 --> 00:02:30,61 process 19 00:02:30,61 --> 00:02:35,88 and how it brings a picture to you is explained by this diagram originated by Dr 20 00:02:35,88 --> 00:02:38,33 meis when you look at an object in real life. 21 00:02:38,63 --> 00:02:44,04 The brain at number one receives an image of it through the eye in photography the 22 00:02:44,04 --> 00:02:49,54 object is a large black text two is image by a lens on a light sensitive film 23 00:02:49,54 --> 00:02:54,19 and three. The exposure period produces a latent image on the film 24 00:02:54,19 --> 00:02:59,78 and four after developing in fixing. A visible negative image is formed at five. 25 00:02:59,93 --> 00:03:03,94 It is called a negative image because it is right where the original object is 26 00:03:03,94 --> 00:03:05,09 black and vice versa. 27 00:03:06,35 --> 00:03:08,09 In order to obtain an image in which the light 28 00:03:08,09 --> 00:03:13,15 and dark areas are in the correct relationship this process must be repeated the 29 00:03:13,15 --> 00:03:15,80 negative is therefore photographed or printed. 30 00:03:16,15 --> 00:03:18,06 Light shines through the negative 31 00:03:18,06 --> 00:03:20,70 and falls upon another light sensitive film at six 32 00:03:21,52 --> 00:03:25,21 and produces a latent image it's seven once more of the developing 33 00:03:25,21 --> 00:03:29,56 and fixing of the film we veil a permanent image at eight which is this time a 34 00:03:29,56 --> 00:03:31,99 positive image of the original object. 35 00:03:32,01 --> 00:03:32,60 Therefore 36 00:03:32,60 --> 00:03:37,46 when this positive image at nine is alumina eight in the brain a ten again sees an 37 00:03:37,46 --> 00:03:40,79 image which is a faithful reproduction of that obtained from the original subject. 38 00:03:43,42 --> 00:03:46,59 What happens to the film chemically may be expressed in three equation. 39 00:03:46,91 --> 00:03:50,52 First a latent images form a second. 40 00:03:50,70 --> 00:03:54,57 It is developed and finally made permanent. 41 00:03:56,71 --> 00:03:59,69 The photographic emotion is made up of millions of tiny. 42 00:04:00,00 --> 00:04:04,98 Crystals of silver bromide suspended in a thin layer of Delton This picture shows 43 00:04:04,98 --> 00:04:09,00 how the crystals actually look when magnified several thousand times. 44 00:04:09,02 --> 00:04:12,95 We want to talk about them for a few minutes in rather technical language. 45 00:04:12,97 --> 00:04:18,68 Because on their peculiar properties is based the whole art photography you will 46 00:04:18,68 --> 00:04:22,72 note that the triangle is a typical shape in this group. And for simplicity. 47 00:04:22,74 --> 00:04:27,89 We shall talk about a single triangular Crystal. 48 00:04:27,91 --> 00:04:30,34 This crystal is made up of a pattern of silver 49 00:04:30,34 --> 00:04:33,56 and Roman irons the silver denoted by a G. 50 00:04:33,56 --> 00:04:34,85 Very positive charge 51 00:04:35,62 --> 00:04:40,85 and the Brahman denoted by B R A negative the significant detail about this crystal 52 00:04:40,85 --> 00:04:46,05 which makes it a photographic value is a tiny speck best known as the sensitivity 53 00:04:46,05 --> 00:04:52,31 spec consisting primarily of silver sulfide these specks probably formed during the 54 00:04:52,31 --> 00:04:56,60 manufacture of the emotion. Let us follow the action. 55 00:04:57,15 --> 00:05:01,66 When light waves from your favorite movie star pass into the camera to the emotion. 56 00:05:01,84 --> 00:05:05,17 If you light quanta strike this particular Crystal. 57 00:05:05,55 --> 00:05:09,71 And when a quantum of proper energy hits a Roman ion it releases 58 00:05:09,71 --> 00:05:15,01 and electron from the Roman leaving it no longer an eye on what an atom with zero 59 00:05:15,01 --> 00:05:19,98 charge the electron is then free to travel within the crystal just as if the 60 00:05:19,98 --> 00:05:21,60 crystal were in the electric conductor. 61 00:05:21,79 --> 00:05:26,20 Indeed we speak of this property of silver bromide crystals as photo conductance 62 00:05:26,90 --> 00:05:29,49 since they conduct electricity when light falls on them. 63 00:05:31,61 --> 00:05:33,47 Electrons within the crystal travel freely 64 00:05:33,47 --> 00:05:38,83 and naturally in their wanderings they find the sensitivity spec since the 65 00:05:38,83 --> 00:05:40,79 molecular pattern of the spec is such 66 00:05:40,79 --> 00:05:45,78 that it can trap the electrons like a positive pole in the crystal the electrons 67 00:05:45,78 --> 00:05:50,13 released by the action of the light find themselves clustered about the sensitivity 68 00:05:50,13 --> 00:05:56,66 spec cumulation of these electrons converts the spec to a negative pole capable of 69 00:05:56,66 --> 00:05:58,93 attracting positively charged particles. 70 00:06:02,74 --> 00:06:07,40 There is at all times within the crystal a movement of ions through the thermal 71 00:06:07,40 --> 00:06:09,16 agitation. 72 00:06:09,18 --> 00:06:11,11 Under ordinary conditions the silver 73 00:06:11,11 --> 00:06:16,17 and Roman irons moved sluggishly about occupying vacant places within the crystal 74 00:06:16,17 --> 00:06:21,07 lattice in this particular Crystal However something has happened to disturb the 75 00:06:21,07 --> 00:06:26,02 normal state after being struck by the light a negative pole was formed at the 76 00:06:26,02 --> 00:06:32,92 sensitivity spec and now positively charged silver ions are attracted to the speck. 77 00:06:32,94 --> 00:06:38,85 We follow the silver ions in their slow path toward the speck since their movement 78 00:06:38,85 --> 00:06:43,26 is due to thermal agitation of the molecules this action is faster 79 00:06:43,26 --> 00:06:45,25 when the crystal is warm than 80 00:06:45,25 --> 00:06:50,55 when it is cold which explains why film is less sensitive in cold weather the 81 00:06:50,56 --> 00:06:52,95 silver ions progressively drawn to the spec 82 00:06:53,71 --> 00:06:55,49 and as fast as they come within its range. 83 00:06:55,63 --> 00:06:58,95 They are neutralized by the electrons clustered about the speck. 84 00:06:59,97 --> 00:07:05,01 Eventually one atom of silver is neutralized respect for each quantum of light 85 00:07:05,01 --> 00:07:05,92 which if the crystal 86 00:07:05,92 --> 00:07:10,75 and the sensitivity spect finds itself surrounded by a group of silver atoms. 87 00:07:11,71 --> 00:07:16,24 It is the aggregate of these clusters of silver present in the crystals which were 88 00:07:16,24 --> 00:07:21,58 struck by light which are the latent image in the film this image is called latent 89 00:07:21,58 --> 00:07:26,59 because it is quite invisible and of no use to us until a developer reveals 90 00:07:26,59 --> 00:07:32,90 that the latent images permanent this crystal pattern being stable at ordinary 91 00:07:32,90 --> 00:07:35,12 temperatures and fact. 92 00:07:35,38 --> 00:07:37,54 Film exposed by the Andre expedition 93 00:07:37,54 --> 00:07:40,94 and abandoned in the Arctic was found thirty years later 94 00:07:40,94 --> 00:07:43,74 and developed to give satisfactory pictures. 95 00:07:43,76 --> 00:07:47,04 Following the neutralization of the electrons at the spec by the silver ions 96 00:07:47,04 --> 00:07:50,31 suspect regains its original ability to trap electrons 97 00:07:50,31 --> 00:07:51,95 and on immersion in a developer 98 00:07:51,95 --> 00:07:56,33 and ionized molecule hydroquinone bearing a negative charge is attracted to the 99 00:07:56,33 --> 00:07:59,85 specter or latent image. The secret of the use of certain weight. 100 00:08:00,00 --> 00:08:01,75 Cing agents as developers is 101 00:08:01,75 --> 00:08:04,88 that they're like trick potential is of just the right order to be attracted to the 102 00:08:04,88 --> 00:08:05,23 specs. 103 00:08:05,73 --> 00:08:09,53 But they are not powerful enough to reduce the silver ions in neighboring crystals 104 00:08:09,53 --> 00:08:11,31 which have not been exposed to light. 105 00:08:12,29 --> 00:08:14,48 One molecule of Heidrick unknown appears at the spec 106 00:08:14,48 --> 00:08:17,50 and loses its negative charge which is an electron to the group. 107 00:08:17,76 --> 00:08:22,17 Thus negatively charged the spec is once more the target for wandering silver ions 108 00:08:22,17 --> 00:08:26,36 and as fast as one silver ion arrives at the Spectrum look at lies itself 109 00:08:26,36 --> 00:08:28,16 and leaves the group again positively charged 110 00:08:29,00 --> 00:08:30,77 and not a molecule of hiding going on appears 111 00:08:30,77 --> 00:08:35,24 and deposits another electron if this keeps up long enough all the silver ions 112 00:08:35,24 --> 00:08:37,92 within one crystal are reduced to metallic silver 113 00:08:37,92 --> 00:08:41,92 and we have a black deposit forming part of a visible image. 114 00:08:41,93 --> 00:08:45,23 The bromide ions move out of the crystal and are released in the developer. 115 00:08:47,31 --> 00:08:48,56 To show how a picture of light 116 00:08:48,56 --> 00:08:51,55 and dark tones may result from a collection of silver particles. 117 00:08:51,92 --> 00:08:56,04 Let us see what happens when crystals are given exposures of different intensity. 118 00:08:56,52 --> 00:09:00,46 This crystal receiving much light has many electrons released 119 00:09:00,46 --> 00:09:03,86 and many silver atoms formed following development. 120 00:09:04,06 --> 00:09:10,51 It is completely reduced to metallics over. 121 00:09:10,53 --> 00:09:16,65 The next Crystal receiving a moderate amount of light has fewer ions reduced to 122 00:09:16,65 --> 00:09:21,25 atoms and has some of the silver and Brahman ions left in their places. 123 00:09:21,61 --> 00:09:27,04 The third Crystal receiving little light has few electrons released. 124 00:09:27,30 --> 00:09:33,14 And a few silver atoms formed. 125 00:09:34,58 --> 00:09:37,44 I want three crystals of them have this appearance. 126 00:09:39,73 --> 00:09:43,25 It is necessary to remove these undeveloped silver and bromine ions 127 00:09:43,25 --> 00:09:47,99 and this is accomplished with sodium file sulphate which dissolves the silver 128 00:09:47,99 --> 00:09:51,22 bromide leaving the metallic silver atoms behind. 129 00:09:51,38 --> 00:09:56,65 But the positive silver making up the visible image actually consists of clusters 130 00:09:56,65 --> 00:09:59,84 of these atoms distributed throughout the gelatin layer. 131 00:10:03,42 --> 00:10:06,30 These particles are not evident in an actual picture 132 00:10:06,99 --> 00:10:11,84 but may be seen under enormous magnification as in this photo micrograph 133 00:10:16,78 --> 00:10:20,72 we have seen how the silver bromide crystals receive install the latent image 134 00:10:21,46 --> 00:10:23,46 and learn that a developer is needed to reveal it 135 00:10:23,46 --> 00:10:28,31 and of fixing back to make it permanent in a Hollywood laboratory thousands of 136 00:10:28,31 --> 00:10:30,69 gallons of such developing solutions are in daily use. 137 00:10:31,34 --> 00:10:36,72 They are compounded with the utmost care using purified water untested chemicals. 138 00:10:37,71 --> 00:10:38,88 But what goes into a developer. 139 00:10:40,17 --> 00:10:46,16 First of all we need are using Agent which hydro can own is typical There are a 140 00:10:46,16 --> 00:10:50,44 number of organic reducing agents such as a lawn pyro liason Imanol 141 00:10:50,44 --> 00:10:52,10 and hard to come down. 142 00:10:52,12 --> 00:10:56,61 Which will convert the latent image to metallic silver here we see some hydrophone 143 00:10:56,61 --> 00:10:57,37 added to water 144 00:10:57,37 --> 00:11:01,32 and a piece of exposed film agitated in the solution 145 00:11:12,69 --> 00:11:13,78 but why doesn't it. Develop. 146 00:11:14,13 --> 00:11:18,02 Well the reason nothing happened is because the developer worked only in the 147 00:11:18,02 --> 00:11:22,56 presence of an alkaline therefore we Next add some sodium carbonate to the hard to 148 00:11:22,56 --> 00:11:23,30 pronounce solution. 149 00:11:33,95 --> 00:11:36,61 Now observe that development takes place promptly. 150 00:11:38,59 --> 00:11:39,46 But also observe 151 00:11:39,46 --> 00:11:44,16 that the solution becomes discolored the discoloration is due to the oxidation of 152 00:11:44,16 --> 00:11:44,83 the Heineken own 153 00:11:45,57 --> 00:11:50,76 and a solution like this would lose strength very rapidly to prevent this rapid 154 00:11:50,76 --> 00:11:52,81 oxidation and loss of developing power. 155 00:11:53,35 --> 00:11:57,98 Sodium sulfite is included in the formula to a solution of how to can only first 156 00:11:57,98 --> 00:11:59,86 add some sodium sulfite and then. 157 00:12:00,00 --> 00:12:06,02 The sodium carbonate. 158 00:12:10,57 --> 00:12:11,89 A piece of exposed film 159 00:12:11,89 --> 00:12:15,14 and immersed in the solution will rapidly turn black indicating 160 00:12:15,15 --> 00:12:20,03 that the developing power is unimpaired by the sodium sulfite But now we noticed 161 00:12:20,03 --> 00:12:24,36 that the solution remains perfectly colorless our developing solution is now 162 00:12:24,36 --> 00:12:25,44 practically complete. 163 00:12:25,89 --> 00:12:30,42 It is desirable however to include a small quantity of potassium bromide to 164 00:12:30,42 --> 00:12:33,52 restrain and reducing action of the developer so 165 00:12:33,53 --> 00:12:36,83 that it will convert only the desired I mentioned into metallic silver. 166 00:12:37,31 --> 00:12:42,46 Without affecting the surrounding unexposed so bromide. 167 00:12:42,48 --> 00:12:46,25 The ability of potassium bromide to retard the action of the developer is 168 00:12:46,25 --> 00:12:48,51 illustrated here in an exaggerated way 169 00:12:49,39 --> 00:12:51,54 but its class contain complete developing solutions 170 00:12:51,54 --> 00:12:55,25 and excessive amount of potassium bromide has been added to the one on the left. 171 00:13:00,17 --> 00:13:04,37 Now we see that the solution with the excess throw mine does not develop at all. 172 00:13:10,29 --> 00:13:14,61 These then are the ingredients of a developing a the developing or reducing agent. 173 00:13:14,82 --> 00:13:17,77 Say the preservative see the alkali 174 00:13:17,77 --> 00:13:23,97 or activator the restrainer in addition to a developer we need affecting bad 175 00:13:23,97 --> 00:13:28,46 containing sodium five sulphate to remove the undeveloped silver bromide by 176 00:13:28,46 --> 00:13:33,46 converting it to soluble Silver Fire sulphate the primary function of the faking 177 00:13:33,46 --> 00:13:39,75 bath therefore is to remove the unexposed undeveloped silver brown line this action. 178 00:13:39,87 --> 00:13:42,80 Not only makes the film transparent where there is no M. 179 00:13:42,80 --> 00:13:44,99 and It also makes the image permanent. 180 00:13:45,59 --> 00:13:50,01 Since the action of light by itself will gradually cause the UN removed silver 181 00:13:50,01 --> 00:13:54,20 bromide to darken in this demonstration we observe 182 00:13:55,09 --> 00:13:59,93 that a piece of undeveloped film becomes transparent. When agitated. 183 00:14:00,00 --> 00:14:03,13 And a strong solution of hypo. 184 00:14:03,15 --> 00:14:21,20 Because the silver bromide is converted to soluble so versatile sulphate. 185 00:14:22,31 --> 00:14:25,69 You want. We call that development was carried out in an alkaline solution. 186 00:14:26,02 --> 00:14:29,96 It is therefore desirable to make the fixing bath acid in reaction. 187 00:14:30,17 --> 00:14:33,92 So that development will stop promptly when the film is immersed in it.